Sedimentation of solid particles in liquid materials, like paints and inks, is caused by gravitational force pulling particles of high density down. In the worst case, sedimentation can result in settling, the formation of a hard layer of solid material on the bottom of the can. How to avoid this?
Sedimentation can be prevented by assuring that a reversible three-dimensional network of sufficient strength is present in the material. Such a network can be introduced by using a suitable rheology additive, often referred to as thickener, in the formulation. In this short series of blog posts focusing on sedimentation stability I will give you some guidance on the key aspects of sedimentation and how to predict it.
The strength of a three-dimensional network in a water-based paint can be quantified by determining the yield stress, also called yield value or yield point, of that paint. The yield stress (
The paint behaves as a stable elastic solid as long as the applied stress is weaker than the yield stress of the paint. In practice, this implies that solid particles in a paint will not sink during storage when the yield stress is high enough. Knowing the yield stress of a paint is therefore important when stability against sedimentation must be predicted. A paint with a high yield stress has a strong network inside, thus assuring storage stability.
It is not easy to determine the yield stress of a material. Moreover, the value of yield stress that is found depends on the experiment done: different methods give different values.
Many materials, including most paints, show viscoelastic behaviour. A viscoelastic material behaves partly as an elastic solid and partly as a viscous liquid.
A viscoelastic material will show shear deformation when shear stress (
A material that behaves as a flowing liquid has a G” that is much higher than its G’. The G’ value of a viscoelastic material is a quantification of the strength of the physical network that is present within the system: a high G’ value indicates that the physical network within the system is strong.
Sedimentation during storage is a process that takes place at low shear stress for a long time. During storage the physical network must be strong enough to prevent solid particles to sink because of gravity.
In order to obtain information about viscoelastic materials, like paints and pigment dispersions, often oscillatory tests are done in which the applied shear stress
Figure 1: Behavior of Gʹ and Gʺ of a viscoelastic material with a gel structure.
The first pre-condition for having stability against sedimentation is that the material is a gel. This implies that the viscoelastic material shows more elastic (‘solid’) behavior than viscous (‘liquid’) behavior: G’ of a gel is higher than its G”. Secondly, both Gʹ and Gʺ must be constant at low shear stress, implying that both properties are independent of shear stress. At a certain shear stress level, the linear behavior of Gʹ is lost. The yield stress of a material (
The higher the G’ value of a paint (in the region in which G’ is constant) and the higher its yield stress, the stronger its resistance against sedimentation.
The values of G’ and yield stress of a material that are measured depend on the history of the material and on how the measurement was done. It is therefore important to always specify how the experiment was carried out.
In the next Blog Post we will discuss what this theory about sedimentation stability means in practice. We will discuss yield stress and storage modulus of waterbased white pigment dispersions, as used in the coatings industry. We will show how both key properties are influenced by using Exilva, a bio-based rheology additive designed for waterbased paints and pigment dispersions.
While waiting, feel free to download our bulletin on the topic:
Reference:
1. The Rheology Handbook, Thomas G. Mezger, 4th edition, 2014.